{"id":1375,"date":"2017-05-16T14:48:52","date_gmt":"2017-05-16T06:48:52","guid":{"rendered":"https:\/\/www.cililun.com\/?p=1375"},"modified":"2017-05-16T20:53:52","modified_gmt":"2017-05-16T12:53:52","slug":"zhong_ke_yuan_he_fei_yan_jiu_yuan_zai_re_dian_cai","status":"publish","type":"post","link":"https:\/\/www.cililun.com\/zhong_ke_yuan_he_fei_yan_jiu_yuan_zai_re_dian_cai\/","title":{"rendered":"\u4e2d\u79d1\u9662\u5408\u80a5\u7814\u7a76\u9662\u5728\u70ed\u7535\u6750\u6599\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u8fdb\u5c55"},"content":{"rendered":"<div>\n<div>&nbsp; &nbsp;\u8fd1\u671f\uff0c<a href=\"https:\/\/www.cililun.com\/tag\/zhong-guo\" title=\"\u4e2d\u56fd\" target=\"_blank\">\u4e2d\u56fd<\/a><a href=\"https:\/\/www.cililun.com\/tag\/ke-xue\" title=\"\u79d1\u5b66\" target=\"_blank\">\u79d1\u5b66<\/a>\u9662\u5408\u80a5\u7269\u8d28<a href=\"https:\/\/www.cililun.com\/tag\/ke-xue\" title=\"\u79d1\u5b66\" target=\"_blank\">\u79d1\u5b66<\/a>\u7814\u7a76\u9662\u56fa\u4f53\u7269\u7406\u7814\u7a76\u6240\u79e6\u6653\u82f1\u7814\u7a76\u5c0f\u7ec4\u5728\u70ed\u7535\u6750\u6599\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u79ef\u6781\u8fdb\u5c55\u3002\u76f8\u5173\u6210\u679c\u5df2\u53d1\u8868\u5728J.Mater. Chemisty A\uff082015, 3, 11768\uff09\u53caJ.Mater. Chemisty C ( 2015, 3, 7045 &#8211; 7052)\u4e0a\u3002 <\/p>\n<div>\u3000\u3000<\/div>\n<div>\u3000\u3000\u70ed\u7535\u6750\u6599\u53ef\u4ee5\u5c06\u70ed\u80fd\u548c\u7535\u80fd\u8fdb\u884c\u76f4\u63a5\u8f6c\u6362\u800c\u65e0\u9700\u8fd0\u52a8\u90e8\u4ef6\uff0c\u4e5f\u4e0d\u6392\u653e\u4efb\u4f55\u6709\u6bd2\u6216\u6e29\u5ba4\u6c14\u4f53\uff1b\u5b83\u53ef\u5229\u7528\u5e9f\u70ed\u53d1\u7535\u4e5f\u53ef\u7528\u4e8e\u56fa\u6001\u5236\u51b7\u3002\u4f46\u76ee\u524d\u70ed\u7535\u6750\u6599\u7684\u8f6c\u6362\u6548\u7387(\u7528\u65e0\u91cf\u7eb2\u4f18\u503cZT\u8868\u5f81)\u8f83\u4f4e\uff08&le;1\uff09\uff0c\u96be\u4ee5\u5927\u89c4\u6a21\u5546\u4e1a\u5e94\u7528\u3002\u56e0\u6b64\u5982\u4f55\u63d0\u9ad8\u5176ZT\u503c\u662f\u76ee\u524d\u70ed\u7535\u6750\u6599\u9886\u57df\u7814\u7a76\u7684\u7126\u70b9\u548c\u91cd\u70b9\u3002<\/div>\n<div>\u3000\u3000<\/div>\n<div>\u3000\u3000&beta;-Zn4Sb3\u662f\u4e00\u79cd\u5177\u6709\u6f5c\u529b\u7684\u73af\u5883\u53cb\u597d\u578b\u9ad8\u6027\u80fd\u70ed\u7535\u6750\u6599\u3002\u901a\u8fc7\u8bf1\u5bfc\u7535\u5b50\u6001\u5bc6\u5ea6(DOS)\u5171\u632f\u7578\u53d8\u662f\u4e00\u79cd\u6709\u6548\u63d0\u9ad8\u70ed\u7535\u6750\u6599\u7684\u70ed\u7535\u52bfS\u5e76\u63d0\u5347\u70ed\u7535\u4f18\u503cZT\u7684\u9014\u5f84\u3002\u79e6\u6653\u82f1\u9886\u5bfc\u7684\u7814\u7a76\u7ec4\u53ca\u5176\u5408\u4f5c\u8005\u6700\u8fd1\u7684\u5b9e\u9a8c\u7814\u7a76\u8868\u660e\uff0c\u5143\u7d20Gd\u63ba\u6742\u5f15\u8d77&beta;-Zn4Sb3\u8d39\u7c73\u80fd\u7ea7\u9644\u8fd1DOS\u7684\u5171\u632f\u7578\u53d8\uff0c\u8868\u73b0\u4e3aDOS\u6709\u6548\u8d28\u91cf\u7684\u5927\u5e45\u589e\u52a0\uff1b\u4f4e\u6e29\u6bd4\u70ed\u7684<a href=\"https:\/\/www.cililun.com\/tag\/celiang\/\" title=\"\u70b9\u51fb\u4e86\u89e3\u66f4\u591a\u5173\u4e8e[\u6d4b\u91cf]\u7684\u6587\u7ae0\" target=\"_blank\">\u6d4b\u91cf<\/a>\u8bc1\u5b9e\u4e86DOS\u5171\u632f\u7578\u53d8\u7684\u53d1\u751f\uff1b\u7b2c\u4e00\u539f\u7406\u8ba1\u7b97\u8fdb\u4e00\u6b65\u63ed\u793a\u51fa\uff0c&beta;-Zn4Sb3\u4ef7\u5e26\u9876\u9644\u8fd1\u51fa\u73b0\u7684\u6001\u5bc6\u5ea6\u5171\u632f\u5cf0\u4e3b\u8981\u6765\u81eaGd\u539f\u5b50\u4e2dd\u8f68\u9053\u7535\u5b50\u7684\u8d21\u732e\u3002\u7531\u4e8e\u8fd9\u79cd\u6001\u5bc6\u5ea6\u5171\u632f\u7578\u53d8\uff0c\u4f7f\u5f97&beta;-(Zn1-xGdx)4Sb3 (x=0.002, 0.003)\u7684\u70ed\u7535\u52bf\u589e\u52a0\u4e86~40&mu;VK-1\uff0c\u540c\u65f6Gd\u63ba\u6742\u5bfc\u81f4x=0.002\u6837\u54c1\u7684\u70ed\u5bfc\u7387\u964d\u4f4e\u4e86\u7ea615%\uff0c\u6700\u7ec8\u4f7f\u5f97&beta;-(Zn1-xGdx)4Sb3 (x=0.002)\u6837\u54c1\u7684ZT\u503c\u5728655K\u8fbe\u5230\u4e861.2\uff0c\u4e0e\u672a\u63ba\u6742\u6837\u54c1(ZT=0.75)\u76f8\u6bd4\u63d0\u9ad8\u4e8660\uff05\u3002\u6b64\u7ed3\u679c\u8868\u660e\uff0cGd\u63ba\u6742\u662f\u4e00\u79cd\u5f15\u8d77DOS\u5171\u632f\u7578\u53d8\u3001\u5e76\u6709\u6548\u63d0\u5347&beta;-Zn4Sb3\u70ed\u7535\u6027\u80fd\u7684\u65b9\u6cd5\u3002\u6b64\u5de5\u4f5c\u6700\u8fd1\u53d1\u8868\u4e8eJ. Mater. Chemistry A (2015, 3, 11768)\u3002<\/div>\n<div>&nbsp;<\/div>\n<div>\u3000\u3000\u53e6\u5916\uff0cBiSbTe\u662f\u76ee\u524d\u6700\u597d\u7684\u5ba4\u6e29\u9644\u8fd1\u7684\u70ed\u7535\u6750\u6599\uff0c\u4e5f\u662f\u552f\u4e00\u5546\u4e1a\u5316\u5e94\u7528\u7684\u5ba4\u6e29\u5236\u51b7\u70ed\u7535\u6750\u6599\u3002\u4f46\u5982\u4f55\u63d0\u9ad8\u5176\u5728100-200oC\u9644\u8fd1\u7684\u70ed\u7535\u6027\u80fd\u4ee5\u7528\u4e8e\u4f4e\u7ea7\u5e9f\u70ed\u53d1\u7535\u662f\u6781\u5177\u6311\u6218\u6027\u548c\u7ecf\u6d4e\u6548\u76ca\u7684\u8bfe\u9898\u3002\u79e6\u6653\u82f1\u9886\u5bfc\u7684\u7814\u7a76\u7ec4\u53ca\u5176\u5408\u4f5c\u8005\u6700\u8fd1\u7684\u7814\u7a76\u8868\u660e\uff0c\u5728BiSbTe\u57fa\u4f53\u4e2d\u590d\u54081vol.% Cu3SbSe4 \u7eb3\u7c73\u9897\u7c92\u4ee5\u5f62\u6210\u7eb3\u7c73\u590d\u5408\u6750\u6599\u3002\u9664\u4e86\u7ea650%\u7684\u6676\u683c\u70ed\u5bfc\u7387\u964d\u4f4e\u5916\uff0c\u7531\u4e8e\u5f02\u8d28\u7ed3\u754c\u9762\u52bf\u7684\u6563\u5c04\u5f15\u8d77\u80fd\u91cf\u8fc7\u6ee4\u6548\u5e94\u4f7f\u70ed\u7535\u52bf\u7387\u5347\u9ad8\u4ee5\u53ca<a href=\"https:\/\/www.cililun.com\/tag\/gaowen\/\" title=\"\u70b9\u51fb\u4e86\u89e3\u66f4\u591a\u5173\u4e8e[\u9ad8\u6e29]\u7684\u6587\u7ae0\" target=\"_blank\">\u9ad8\u6e29<\/a>\u533a\u8fc1\u79fb\u7387\u964d\u4f4e\u7684\u51cf\u7f13\uff0c\u4f7f\u5f97\u529f\u7387\u56e0\u5b50\u5728476K\u65f6\u8fbe\u523037mWcm-1K-2 \uff0c\u800c\u5176ZT\u503c\u8fbe\u52301.6\uff0c\u5b83\u662f\u76ee\u524d\u62a5\u9053\u7684\u5728\u8be5\u6e29\u533a\u7684\u6700\u5927\u503c\u3002\u6b64\u5916\uff0c\u8be5\u6750\u6599\u5728300K\u81f3500K\u7684\u5bbd\u5e7f\u6e29\u5ea6\u8303\u56f4\u5185\u90fd\u5177\u6709\u9ad8ZT\u503c(\u5982\u5728300K ZT=1.0\u800c\u5728500K ZT=1.5)\uff0c\u4f7f\u5f97\u8be5\u6750\u6599\u5728\u4f4e\u7ea7\u5e9f\u70ed<a href=\"https:\/\/www.cililun.com\/tag\/hui-shou\" title=\"\u56de\u6536\" target=\"_blank\">\u56de\u6536<\/a>\u5e94\u7528\u4e0a\u5177\u6709\u8bf1\u4eba\u7684\u5e94\u7528\u524d\u666f\u3002<\/div>\n<\/div><\/div>\n<p><center><img\n<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; &nbsp;\u8fd1\u671f\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5408\u80a5\u7269\u8d28\u79d1\u5b66\u7814\u7a76\u9662\u56fa\u4f53\u7269\u7406\u7814\u7a76\u6240\u79e6\u6653\u82f1\u7814\u7a76\u5c0f\u7ec4\u5728\u70ed\u7535\u6750\u6599\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u79ef\u6781\u8fdb\u5c55\u3002\u76f8\u5173\u6210\u679c\u5df2\u53d1\u8868\u5728J.Mater. Chemisty A\uff082015, 3, 11768\uff09\u53caJ.Mater. Chemisty C ( 2015, 3, 7045 &#8211; 7052)\u4e0a\u3002 \u3000\u3000 \u3000\u3000\u70ed\u7535\u6750\u6599\u53ef\u4ee5\u5c06\u70ed\u80fd\u548c\u7535\u80fd\u8fdb\u884c\u76f4\u63a5\u8f6c\u6362\u800c\u65e0\u9700\u8fd0\u52a8\u90e8\u4ef6\uff0c\u4e5f\u4e0d\u6392\u653e\u4efb\u4f55\u6709\u6bd2\u6216\u6e29\u5ba4\u6c14\u4f53\uff1b\u5b83\u53ef\u5229\u7528\u5e9f\u70ed\u53d1\u7535\u4e5f\u53ef\u7528\u4e8e\u56fa\u6001\u5236\u51b7\u3002\u4f46\u76ee\u524d\u70ed\u7535\u6750\u6599\u7684\u8f6c\u6362\u6548\u7387(\u7528\u65e0\u91cf\u7eb2\u4f18\u503cZT\u8868\u5f81)\u8f83\u4f4e\uff08&le;1\uff09\uff0c\u96be\u4ee5\u5927\u89c4\u6a21\u5546\u4e1a\u5e94\u7528\u3002\u56e0\u6b64\u5982\u4f55\u63d0\u9ad8\u5176ZT\u503c\u662f\u76ee\u524d\u70ed\u7535\u6750\u6599\u9886\u57df\u7814\u7a76\u7684\u7126\u70b9\u548c\u91cd\u70b9\u3002 \u3000\u3000 \u3000\u3000&beta;-Zn4Sb3\u662f\u4e00\u79cd\u5177\u6709\u6f5c\u529b\u7684\u73af\u5883\u53cb\u597d\u578b\u9ad8\u6027\u80fd\u70ed\u7535\u6750\u6599\u3002\u901a\u8fc7\u8bf1\u5bfc\u7535\u5b50\u6001\u5bc6\u5ea6(DOS)\u5171\u632f\u7578\u53d8\u662f\u4e00\u79cd\u6709\u6548\u63d0\u9ad8\u70ed\u7535\u6750\u6599\u7684\u70ed\u7535\u52bfS\u5e76\u63d0\u5347\u70ed\u7535\u4f18\u503cZT\u7684\u9014\u5f84\u3002\u79e6\u6653\u82f1\u9886\u5bfc\u7684\u7814\u7a76\u7ec4\u53ca\u5176\u5408\u4f5c\u8005\u6700\u8fd1\u7684\u5b9e\u9a8c\u7814\u7a76\u8868\u660e\uff0c\u5143\u7d20Gd\u63ba\u6742\u5f15\u8d77&beta;-Zn4Sb3\u8d39\u7c73\u80fd\u7ea7\u9644\u8fd1DOS\u7684\u5171\u632f\u7578\u53d8\uff0c\u8868\u73b0\u4e3aDOS\u6709\u6548\u8d28\u91cf\u7684\u5927\u5e45\u589e\u52a0\uff1b\u4f4e\u6e29\u6bd4\u70ed\u7684\u6d4b\u91cf\u8bc1\u5b9e\u4e86DOS\u5171\u632f\u7578\u53d8\u7684\u53d1\u751f\uff1b\u7b2c\u4e00\u539f\u7406\u8ba1\u7b97\u8fdb\u4e00\u6b65\u63ed\u793a\u51fa\uff0c&beta;-Zn4Sb3\u4ef7\u5e26\u9876\u9644\u8fd1\u51fa\u73b0\u7684\u6001\u5bc6\u5ea6\u5171\u632f\u5cf0\u4e3b\u8981\u6765\u81eaGd\u539f\u5b50\u4e2dd\u8f68\u9053\u7535\u5b50\u7684\u8d21\u732e\u3002\u7531\u4e8e\u8fd9\u79cd\u6001\u5bc6\u5ea6\u5171\u632f\u7578\u53d8\uff0c\u4f7f\u5f97&beta;-(Zn1-xGdx)4Sb3 (x=0.002, 0.003)\u7684\u70ed\u7535\u52bf\u589e\u52a0\u4e86~40&mu;VK-1\uff0c\u540c\u65f6Gd\u63ba\u6742\u5bfc\u81f4x=0.002\u6837\u54c1\u7684\u70ed\u5bfc\u7387\u964d\u4f4e\u4e86\u7ea615%\uff0c\u6700\u7ec8\u4f7f\u5f97&beta;-(Zn1-xGdx)4Sb3 (x=0.002)\u6837\u54c1\u7684ZT\u503c\u5728655K\u8fbe\u5230\u4e861.2\uff0c\u4e0e\u672a\u63ba\u6742\u6837\u54c1(ZT=0.75) [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[138,73,225,174,227],"_links":{"self":[{"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/posts\/1375"}],"collection":[{"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/comments?post=1375"}],"version-history":[{"count":0,"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/posts\/1375\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/media?parent=1375"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/categories?post=1375"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/tags?post=1375"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}